Statistical strategy for stereospecific hydrogen NMR assignments: Validation procedures for the floating prochirality method

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Statistical strategy for stereospecific hydrogen NMR assignments: validation procedures for the floating prochirality method.

We examine the statistical and other considerations which determine the validity and reproducibility of stereospecific hydrogen NMR assignments obtained by the floating prochirality method. In this method, the assignment of a prochiral configuration of hydrogens at selected centers is allowed to 'float' during the structure refinement, and the distribution of prochiral orientations in highly re...

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ژورنال

عنوان ژورنال: Journal of Biomolecular NMR

سال: 1993

ISSN: 0925-2738,1573-5001

DOI: 10.1007/bf00198371